ÎïÀí»¯Ñ§ÊµÑ鱨¸æ

ÁÉÄþ¿Æ¼¼´óѧ ²ÄÁÏÓëÒ±½ð ѧԺ 20xxÄê10ÔÂ6ÈÕ

- 2 -

- 3 -

- 4 -

- 5 -

- 6 -

µÚ¶þƪ£ºÈ¼ÉÕÈȺÍÖкÍÈÈ

ȼÉÕÈȺÍÖкÍÈÈ

Ò»¡¢Ñ¡ÔñÌ⣨ÿСÌâ2·Ö£¬¹²18·Ö¡£Ã¿Ð¡ÌâÓÐ1¡«2¸öÕýÈ·´ð°¸£©

1£®ÏÂÁÐ˵·¨ÖУ¬ÕýÈ·µÄÊÇ

A£®1 mol H2SO4Óë1 mol Ba£¨OH£©2ÍêÈ«ÖкÍËù·Å³öµÄÈÈÁ¿ÎªÖкÍÈÈ

B£®Öкͷ´Ó¦¶¼ÊÇ·ÅÈÈ·´Ó¦¡£

C£®ÔÚ101 kPaʱ£¬1 mol̼ȼÉÕËù·Å³öµÄÈÈÁ¿Ò»¶¨½Ð̼µÄȼÉÕÈÈ

D£®COȼÉÕÊÇÎüÈÈ·´Ó¦

2£®ÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ

A£®ÔÚ101 kPaʱ£¬1 molÎïÖÊÍêȫȼÉÕʱËù·Å³öµÄÈÈÁ¿£¬½Ð×ö¸ÃÎïÖʵÄȼÉÕÈÈ

B£®ËáºÍ¼î·¢ÉúÖкͷ´Ó¦Éú³É1 molË®£¬ÕâʱµÄ·´Ó¦ÈȽÐÖкÍÈÈ

C£®È¼ÉÕÈÈ»òÖкÍÈÈÊÇ·´Ó¦ÈȵÄÖÖÀàÖ®Ò»

D£®ÔÚÏ¡ÈÜÒºÖУ¬1 mol CH3COOHºÍ1 mol NaOHÍêÈ«ÖкÍʱ·Å³öµÄÈÈÁ¿Îª57£®3 kJ

3£®ÒÑÖªÏÂÁÐÈÈ»¯Ñ§·½³Ìʽ£º

2H2£¨g£©£«O2£¨g£©===2H2O£¨g£©£»¦¤H=£­483£®6 kJ/mol H2£¨g£©£«1O2£¨g£©===H2O£¨g£©£»¦¤H=£­241£®8 kJ/mol 2

- 1 -

H2£¨g£©£«1O2£¨g£©===H2O£¨l£©£»¦¤H=£­285£®8 kJ/mol

2

ÔòÇâÆøµÄȼÉÕÈÈΪ A£®£­438£®6 kJ/mol C£®£­285£®8 kJ/mol

2

B£®£­241£®8 kJ/mol D£®ÎÞ·¨È·¶¨

4£®ÒÑÖªZn£¨s£©£«1O£¨===ZnO£¨s£©£»¦¤H=£­350 kJ/mol£¬2g£©Ôò1 g ZnÔÚÑõÆøÖÐȼÉշųöµÄÈÈÁ¿Ô¼Îª

A£®5£®4 kJ C£®3£®5 kJ

B£®350 kJ D£®8£®5 kJ

5£®ÒÑÖª£ºC£¨s£©£«O2£¨g£©===CO2£¨g£©£»¦¤H=£­393£®5 kJ/mol£¬

2H2£¨g£©£«O2£¨g£©===2H2O£¨g£©£»¦¤H=£­483£®6 kJ/mol£¬ ÏÖÓÐ0£®2 molµÄÌ¿·ÛºÍÇâÆø×é³ÉµÄÐü¸¡Æø£¬Òò»ìºÏÎïÔÚÑõÆøÖÐÍêȫȼÉÕ£¬¹²·Å³ö63£®53 kJÈÈÁ¿£¬Ôò»ìºÏÎïÖÐCÓëH2µÄÎïÖʵÄÁ¿Ö®±ÈΪ

A£®1¡Ã1 C£®2¡Ã3

B£®1¡Ã2 D£®3¡Ã2

6£®ÒÑÖª£ºCH4£¨g£©£«2O2£¨g£©===CO2£¨g£©£«2H2O£¨l£©£»¦¤H1=£­Q1£¬

H2£¨g£©£«1O2£¨g£©===H2O£¨g£©£»¦¤H2=£­Q2£¬

2

H2£¨g£©£«1O2£¨g£©===H2O£¨l£©£»¦¤H3=£­Q3£¬

2

³£ÎÂÏÂÈ¡Ìå»ý±ÈΪ4¡Ã1µÄ¼×ÍéºÍÇâÆøµÄ»ìºÏÆøÌå11£®2 L£¨ÒÑÕۺϳɱê×¼×´¿ö£©¾­ÍêȫȼÉÕ»Ö¸´µ½³£Î£¬·Å³öµÄÈÈÁ¿

- 2 -

Ϊ

A£®0£®4Q1£«0£®05Q2 B£®0£®4Q1£«0£®1Q2

C£®0£®4Q1£«0£®05Q3 D£®0£®4Q1£«0£®1Q3

7£®¸ù¾ÝÈÈ»¯Ñ§·½³Ìʽ£¨ÔÚ101 kPaʱ£©£ºS£¨s£©£«O2£¨g£©===SO2£¨g£©£»¦¤H=£­297£®23 kJ/mol£¬·ÖÎöÏÂÁÐ˵·¨Öв»ÕýÈ·µÄÊÇ

A£®SµÄȼÉÕÈÈΪ297£®23 kJ/mol

B£®S£¨g£©£«O2£¨g£©===SO2£¨g£©·Å³öµÄÈÈÁ¿´óÓÚ297£®23 kJ

C£®S£¨g£©£«O2£¨g£©===SO2£¨g£©·Å³öµÄÈÈÁ¿Ð¡ÓÚ297£®23 kJ

D£®ÐγÉ1 mol SO2µÄ»¯Ñ§¼üËùÊͷŵÄ×ÜÄÜÁ¿´óÓÚ¶ÏÁÑ1 mol S£¨s£©ºÍ1 mol O2£¨g£©µÄ»¯Ñ§¼üËùÎüÊÕµÄ×ÜÄÜÁ¿

8£®ÌìÈ»Æø¡¢Ê¯ÓÍ¡¢ÃºµÈÔÚµØÇòÉϵÄÔ̲ØÁ¿ÊÇÓÐÏ޵ģ¬ÔòÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ

¢Ù¿É¿³·¥Ê÷ľ¡¢Ò°²Ý×÷ÄÜÔ´ ¢Ú¿ÉÓþƾ«×÷ÄÜÔ´ ¢Û¿ÉÀûÓõç½âË®µÄ·½·¨ÖƵÃÇâÆø×÷ÄÜÔ´ ¢ÜÓ¦¿ª·¢Ì«ÑôÄÜ¡¢ºËÄܵÈÐÂÄÜÔ´ ¢Ý´óÁ¿Ó¦Ó÷çÄÜ¡¢Ë®ÄܵȿÉÔÙÉúÄÜÔ´

A£®¢Ù

D£®¢Ü¢Ý

9£®ÒÑÖª

2H2£¨g£©£«O2£¨g£©===2H2O£¨l£©£»¦¤H=£­569£®6 kJ¡¤mol1£¬ £­ B£®¢Ù¢Ý C£®¢Ú¢Û - 3 -

2H2O£¨g£©===2H2£¨g£©£«O2£¨g£©£»¦¤H=£«482£®1 kJ¡¤mol1¡££­ÏÖÓÐ1 gҺ̬H2O£¬Õô·¢Ê±ÎüÊÕµÄÈÈÁ¿ÊÇ

A£®2£®43 kJ

C£®43£®8 kJ B£®4£®86 kJ D£®87£®5 kJ

¶þ¡¢Ìî¿ÕÌ⣨12·Ö£©+

10£®¼ÒÓÃÒº»¯ÆøÖÐÖ÷Òª³É·ÖÖ®Ò»ÊǶ¡Íé¡£ÔÚ101 kPaʱ£¬10 kg¶¡ÍéÍêȫȼÉÕÉú³ÉCO2ºÍH2O£¨l£©·Å³öÈÈÁ¿5¡Á105 kJ£¬¶¡ÍéµÄȼÉÕÈÈΪ___________£¬¶¡ÍéȼÉÕµÄÈÈ»¯Ñ§·½³ÌʽΪ________________________________________________¡£

11£®1£®00 L 1£®00 mol¡¤L1 H2SO4ÈÜÒºÓë2£®00 L 1£®00 mol¡¤L£­

£­1 NaOHÈÜÒºÍêÈ«·´Ó¦£¬·Å³ö114£®6 kJµÄÈÈÁ¿£¬ÓÉ´Ë¿ÉÍÆÖªH2SO4ÓëNaOH·¢ÉúÖкͷ´Ó¦µÄÖкÍÈÈΪ___________£¬±íʾ¸ÃÖкÍÈȵÄÈÈ»¯Ñ§·½³ÌʽΪ___________¡£

- 4 -

²Î¿¼´ð°¸

Ò»¡¢1£®B 2£®C 3£®C 4£®A 5£®A 6£®D 7£®C 8£®D

9£®Aª¥

¶þ¡¢10£®2900 kJ/mol 2C4H10£¨g£©£«13O2£¨g£©===8CO2£¨g£©£«10H2O£¨l£©£»¦¤H=£­5800 kJ/mol 11£®57£®3 kJ/mol

1H2SO4£¨aq£©£«NaOH£¨aq£©=== 1Na2SO4£¨aq£©£«H2O22

£¨l£©£»¦¤H=£­57£®3 kJ/mol

- 5 -