研究计划书

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研究计划书

第二篇：从前辈那里得到的研究计划书模板

]【资源】从前辈那里得到的研究计划书模板

★ ★ ★ ★

小木虫(金币+1):奖励一下，鼓励发有价值的话题

zhangbin07(金币+1):谢谢LZ分享~ 2010-06-11 17:22:52

zshtom(金币+1): 2010-06-11 17:33:13

cds0564(金币+1):谢谢分享~ 2010-06-25 00:57:19

再次对前辈们表示感谢

我也是用这个模板申请成功的

希望对大家有帮助

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因为我纳米盘密码不记得了 暂时把内容贴进来吧 大家需要的可以烤到word里自己排版

我用的是第二个全英文的

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中南大学公派研究生（联合培养博士生）研修计划书

Research Plan for Joint Educational PhD Program, Central South University

姓名Name 姓/Surname： 名/Last name:

性别Gender Male 出生日期Date of birth (yy/mm/dd)

所在学院College School of Chemistry and Chemical Engineering 所学专业

Major Applied Chemistry

国内导师

Domestic supervisor Professor *** 留学国别Hosting foreign country Australia

留学国外大学Hosting foreign University *** 留学院系Hosting faculty or department School of Chemistry

国外导师Hosting foreign supervisor Professor ***

研究领域Area of research Electrochemistry

学习期限/Duration of study 24 months (from ( 2008 yy/ 10 mm/ 1 dd) to ( 2010yy/ 9 mm/ 30dd)

课题研究项目/RESEARCH PROJECT

题目/TITLE: Fabrication and Modification of Different Electrocatalysts of Oxygen Reduction Reaction in Metal/ Air Battery

Keywords: Metal/ air battery, Oxygen reduction reaction, Electrocatalyst, Electrochemistry

研究课题在国内外研究情况及水平THE CURRENT RESEARCH CONDITION AND LEVEL OF THE RESEARCH PROJECT AT HOME AND ABROAD:

The electrocatalysts of oxygen reduction reaction (simply called ORR) are the key electrode materials for the metal/ air battery. Noble metal and alloy, such as Pt

and alloy, are widely used as catalysts because of their highest catalytic activity and most stable performance in all the materials. Considering their high price, however, Pt and alloy are not suitable to be applied in large-scale industry. Therefore, it is significant to find a less expensive catalyst to replace Pt and alloy[1]. Recently three types of transition metal oxides are considered to be the excellent catalysts with wide application prospect due to low cost and high performance. In this essay I will introduce them as follows.

The first type is the series of Manganese oxides. Manganese oxide is cheap and its source is abundant. It has been widely reported that the series of Manganese oxides show well catalytic activity on the decomposition of ORR and H2O2. They are usually prepared by adopting the method of thermal treatment. The temperature of pyrolysis influences greatly the activity of catalysts. L. Jaakko discovers that the activity of MnO2 prepared by using pyrolysis at 500℃ is very well. Z. D. Wei [2] fabricated MnO2 with high catalytic performance by the pyrolysis of Manganese Nitrate at 340℃. The optimal weight ratio of MnO2 in the electrode is 6.7%. T. X. Jiang[3] prepared low cost and high effective electrocatalyst with MnO2 and rare earth chloride. It is shown in the experimental results that the optimal temperature of calcining is 300℃, and the time is 20 hours. It is generally thought that catalytic activity of the series of Manganese oxide in ORR is realized by the Mn(Ⅳ)/Mn(Ⅲ) electrode. The catalytic activity of γ-MnOOH is the highest among a series of Manganese oxide. J. S. Yang[4] synthesised nano finestra amorphism Manganese oxide by adopting the method of low temperature liquid phase redox. Its catalytic activity center is considered to be more than that of crystal MnO2, and this type of material with poriferous structure is more suitable to be used to make poriferous electrode. Perovskite complex metal oxide is another type of catalyst studied by many researchers. The structure of perovskite complex metal oxides is ABO3, of which A is rare earth element and B is transition metal element. Due to its high conductivity (about 104 Ω-1?cm-1) and well ORR electrocatalytic activity, it is a kind of excellent double function ORR catalyst material. It is shown in researches[5] that the catalytic activity of oxide with structure of pure ABO3 is not very high. When

A position is partly replaced by some low valence metal ions, the property of B position ion and vicinal oxygen ion can be improved. Complex valence of B position ion and vacancy of cation can be formed, which heightens the catalytic activity of complex oxide. The catalytic activity is better when A position ion is La or Pr, so the research of this respect is very common. B position ion plays a decisive role in the catalytic activity of this type of oxides. The sequency of catalytic activity is Co>Mn>Ni>Fe>Cr. The catalytic activity is the highest when B position is Fe. Both activity and stability of complex oxides are better when B position is Mn or Ni. There are several methods of fabricating perovskite complex metal oxide. The method of Acetate Decomposition (AD) is used commonly in the early stage. The temperature of calcining is between 800 and 900℃ and time of calcining is as long as about 10 hours. The method of amorphism citric acid precursor (ACP) is a modified method of AD. The temperature of calcining is fall at 600℃ and time is shortened to 2 hours. The sol-gel method can obtain nano material with larger specific surface area and

better catalytic activity. Therefore, it is widely used in the fabrication of perovskite metal oxide catalyst.

Finally, the spinel transition metal oxide is one type of catalyst with bright prospect. The general formula of its molecule is AB2O4. In this type of compound the vacancy of tetrahedron and octahedron and oxygen co-ordination was occupied by the transition metal ion with approximate radius. It is approved by many researchers that the catalytic mechanism of spinel transition metal oxide on ORR is similar with that of perovskite transition metal oxide.

Although there are many kinds of material which can cause catalytic effect on ORR, few can be used in practical industry. The noble metal, such as Pt and alloy, possess high catalytic activity and stability, but it can not be used in large-scale industry because of their expensive price. Transition metal oxides are thought to have a wide application future because of their well catalytic activity, high stability and low cost. However, the catalytic mechanism is still unknown to us. The structure, the component and ratio of elements can not be designed under the direction of theory. Much exploration work need us to finish.

References

[1] Huang Weiguo, Wang Xianyou, Wang Xingyan, Yang Hongping. Research Progress on the Catalyst of Oxygen Reduction Electrode for Metal-Air Battery[J]. Materials Review, 2004, 18(10): 34~36.

[2] Zidong Wei, , Wenzhang Huang, Shengtao Zhang and Jun Tan. Carbon-based air electrodes carrying MnO2 in zinc–air batteries [J]. Journal of Power Sources, 2000, 91(2): 83~85.

[3] Jiang Taixiang, Shi Pengfei, Li Jun. Study on oxygen electrode catalyst for aluminum-air batteries. 1994, 18(2): 23.

[4] Jingsi Yang and Jun John Xu. Nanoporous amorphous manganese oxide as electrocatalyst for oxygen reduction in alkaline solutions [J]. Electrochemistry Communications, 2003, 5(4): 306~311.

[5] Nae-Lih Wu, Wei-Ren Liu and Sern-Jei Su. Effect of oxygenation on electrocatalysis of La0.6Ca0.4CoO3?x in bifunctional air electrode [J]. Electrochimica Acta, 2003, 48(11): 1567~1571.

研究课题的目的及预期目标THE AIM AND EXPECTATION OF THE RESEARCH:

I will engage in the research under the direction of Professor *** at *** University and Professor *** at *** University. They recommended me to research fabrication and modification of different electrocatalysts of oxygen reduction reaction in metal/ air battery, which will be very interesting in the future. Under their direction, theoritically, I will investigate the mechanism of fabrication of transition metal oxide, seek an effective and economical method to prepare the electrocatalyst, get the optimal experimental parameters of preparation process, and I will also explore the mechanism of ORR. During this period I will publish several papers or apply some patents related with my research if possible. And I will finish my dissertation of PhD.

拟留学院校在此学科领域的水平和优势THE LEVEL AND ADVANTAGE OF THE HOSTING FOREIGN INSTITUTION ON THIS PROJECT:

The institution I wants to work in is the school of chemistry at Monash University. It has at least three advantages as follows. Firstly, there are advanced experiment instruments. Facilities in the laboratory are Zeta Potential and Size Analyzer, XRD, XRF, AFM, Electrochemical Impedance Analyzer, Polarization Apparatus, Capillary Electrophoresis, etc. And in the department there are also SEM, TEM, EPMA, etc. Secondly, solid basic research work has been done by the researchers in the laboratory. Great work about the research of electrocatalysts in metal/ air battery has been finished by them. Finally, excellent research environment has formed in the institution. The fabrication technology of electrocatalysts in metal/ air battery is advanced in Australian manufacture. There is frequent cooperation between these manufacturers and the institution, so I can learn the most advanced technology in this field.

回国后工作/学习计划THE STUDY/WORK PLAN AFTER RETURNING TO CHINA:

After I finish my PhD study and return to my home country, I will do some further reserch on the preparation of electrocatalysts in metal/ air battery. I will investigate the most proper method to fabricate the catalysts with high performance. And I wants to grasp the optimal parameters of the production technology. I hope the technology can be applied widely in the industry of my country.

国内导师签字 SIGNATURE OF DOMESTIC SUPERVISOR：

Date(yy/mm/dd):

国外导师签字 SIGNATURE OF HOSTING FOREIGN SUPERVISOR:

Date(yy/mm/dd):

学校审核意见COMMENT OF CHONGQING UNIVERSITY:

负责人签字SIGNATURE OF THE RESPONSIBLE PARTY：

Date(yy/mm/dd):

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Research Plan for PhD Program

Name Surname: Last name:

Gender Date of birth / /

University Department

Domestic supervisor Host country

Host University Host department

Host supervisor Area of research

Duration of study months (from to )

RESEARCH PROJECT

TITLE:

BACKGROUND AND INTRODUCTION OF THE RESEARCH PROJECT:

THE PREPARATION WORK OF THE PROJECT IN CHINA:

THE AIM AND EXPECTATION OF THE RESEARCH PROJECT ABROAD:

THE EXPERIMENTAL METHODS AND DATA ANALYSIS METHODS:

THE SCHEDULE OF THE RESEARCH PROJECT PLAN:

THE WORK PLAN AFTER RETURNING TO CHINA:

SIGNATURE OF HOST SUPERVISOR:

Date:

SIGNATURE OF DOMESTIC SUPERVISOR：

Date: COMMENT OF THE HOST INSTITUTION:

SIGNATURE OF THE RESPONSIBLE PARTY OF THE HOST INSTITUTION：

Date: COMMENT OF FUDAN UNIVERSITY:

SIGNATURE OF THE RESPONSIBLE PARTY UNIVERSITY：

Date: OF FUDAN